Acceptable intake (for subchronic and chronic exposure)
Numbers which describe how toxic a chemical is. The numbers are derived from animal studies of the relationship between dose and non-cancer effects. There are two types of acceptable exposure values: one for acute (relatively short-term) and one for chronic (longer-term) exposure.
A class of compounds that can be corrosive when concentrated. Weak acids, such as vinegar and citric acid, are common in foods. Strong acids, such as muriatic (or hydrochloric), sulfuric and nitric acid have many industrial uses, and can be dangerous to those not used to handling them. Acids are chemical "opposites" of bases, in that they can neutralize each other.
A guideline established by environmental protection agencies to identify the concentration of a substance in a particular medium (water, soil, etc.) that may present a health risk when exceeded. If contaminants are found at concentrations above their action levels, measures must be taken to decrease the contamination.
A term used to describe sludge that contains microorganisms that break down organic contaminants (e.g., benzene) in liquid waste streams to simpler substances such as water and carbon dioxide. It is also the product formed when raw sewage is mixed with bacteria-laden sludge, then stirred and aerated to destroy organic matter.
Molecules of gas, liquid, or dissolved solids that adhere or "stick" to the surfaces they come in contact with. Some chemicals adsorb strongly to soil particles. This differs from absorb: "to take up or make part of the existing whole," like a sponge absorbs (sucks up) water.
Adverse health effects
Effects of chemicals or other materials that impair one's health. They can range from relatively mild temporary conditions such as minor eye or throat irritation, shortness of breath or headaches to permanent and serious conditions such as cancer, birth defects or damage to organs.
The level above which an environmental protection agency suggests it is potentially harmful to be exposed to a contaminant, although no action is mandated.
Passing air through a solid or liquid, often part of a process that promotes breakdown or movement of contaminants in soil or water by exposing them to air.
Injecting air or oxygen into an aquifer to strip or flush volatile contaminants as air bubbles up through the ground water. The air is captured by a vapor extraction system. (See soil vapor extraction).
A treatment system that removes or "strips" volatile organic compounds from contaminated groundwater or surface water by forcing an airstream through the water and causing the compounds to evaporate.
Air stripping tower
Air stripping removes volatile organic chemicals (such as solvents) from contaminated water by causing them to evaporate. Polluted water is sprayed downward through a tower filled with packing materials while air is blown upwards through the tower. The contaminants evaporate into the air, leaving significantly-reduced pollutant levels in the water. The air is treated before it is released into the atmosphere.
Alkaline (synonyms: basic, caustic)
Having the properties of a base, a pH greater than 7. Usually used as an adjective, i.e. "alkaline soil". See Acid, Base,pH
An area of sand, clay or other similar material that has been gradually deposited by moving water, such as along a river bed or shore of a lake.
Refers to the surrounding air. Generally, ambient air refers to air outside and surrounding an air pollution source location. Often used interchangeably with "outdoor air."
In the absence of oxygen. Some organisms, such as certain soil bacteria, thrive under anaerobic conditions in soil.
A chemical being tested for in a laboratory test.
Applicable or Relevant and Appropriate Requirements (ARARs)
Federal or state laws, regulations, standards, criteria or requirements which would apply to the cleanup of hazardous substances at a particular site.
A water-bearing layer of rock or sediment that is capable of yielding useable amounts of water. Drinking water and irrigation wells draw water from the underlying aquifer.
A gray, brittle and highly poisonous metal. It is used as an alloy for metals, especially lead and copper, and is used in insecticides and weed killers. In its inorganic form, it is listed as a cancer-causing chemical under Proposition 65.
A well that flows up like a fountain because of the internal pressure of the aquifer.
A general name given a family of naturally occurring fibrous silicate minerals. Asbestos fibers were used mainly for insulation and as a fire retardant material in ship and building construction and other industries, and in brake shoes and pads for automobiles. Inhaling asbestos fibers has been shown to result in lung disease (asbestosis) and in lung cancer (mesothelioma). The risk of developing mesothelioma is significantly enhanced in smokers.
T o refill an excavated area with uncontaminated soils; and the material used to refill an excavated area.
Background concentration, background level
Represents the average amount of toxic chemicals in the air, water or soil to which people are routinely exposed. More than half of the background concentration of toxic air in metropolitan areas comes from automobiles, trucks and other vehicles. The rest comes from industry and business, agricultural, and from the use of paints, solvents and chemicals in the home.
A class of compounds that are "opposite" to acids, in that they neutralize acids. Weak bases are used in cooking (baking soda) and cleaners. Strong bases can be corrosive, or "caustic". Examples of strong bases that are common around the house are drain cleaners, oven cleaners and other heavy duty cleaning products. Strong bases can be very dangerous to tissue, especially the eyes and mouth.
The continuous solid rock of the continental crust. Bedrock can be found anywhere from the surface to hundreds of feet below ground. Bedrock can be solid or it can contain numerous cracks (fractures). Groundwater and chemicals can move through fractured bedrock.
A very fine clay, expansible when moist, commonly used to provide a tight seal around a monitoring well. Also used in slurry walls.
A petroleum derivative widely used in the chemical industry. A few uses are: synthesis of rubber, nylon, polystyrene, and pesticides; and production of gasoline. Benzene is a highly volatile chemical readily absorbed by breathing, ingestion or contact with the skin. Short-term exposures to high concentrations of benzene may result in death following depression of the central nervous system or fatal disturbances of heart rhythm. Long-term, low-level exposures to benzene can result in blood disorders such as aplastic anemia and leukemia. Benzene is listed as a cancer-causing chemical under Proposition 65.
A curb, ledge, wall or mound used to prevent the spread of contaminants. It can be made of various materials, even earth in certain circumstances. See Alpha particle, Gamma radiation.
The process by which the concentrations of some toxic chemicals gradually increase in living tissue, such as in plants, fish, or people as they breathe contaminated air, drink contaminated water, or eat contaminated food.
A process that uses microorganisms to change toxic compounds into non-toxic ones.
Residuals generated by the treatment of sewage, petroleum refining waste and industrial chemical manufacturing wastewater with activated sludge. See Activated Sludge.
Transformation of one chemical to others by populations of microorganisms in the soil.
Boring (soil boring)
Usually, a vertical hole drilled into the ground from which soil samples can be collected and analyzed to determine the presence of chemicals and the physical characteristics of the soil.
First enacted in 1970 to provide long-term environmental protection, the law requires that governmental decision-makers and public agencies study the significant environmental effects of proposed activities, and that significant avoidable damage be avoided or reduced where feasible. CEQA also requires that the public be told why the lead public agency approved the project as it did, and gives the public a way to challenge the decisions of the agency.
A number, generally expressed in exponential form (i.e., 1 x 10 -6 , which means one in one million), which describes the increased possibility of an individual developing cancer from exposure to toxic materials. Calculations producing cancer risk numbers are complex and typically include a number of assumptions that tend to cause the final estimated risk number to be conservative.
A layer, such as clay or a synthetic material, used to prevent rainwater from penetrating the soil and spreading contamination.
A treatment system in which organic contaminants are removed from groundwater and surface water by forcing it through tanks containing activated carbon, a specially-treated material that retains such compounds. Activated carbon is also used to purify contaminated air by adsorbing the contaminants as the air passes through it.
Carbon tetrachloride (CCl4)
A colorless, nonflammable toxic liquid that was widely used as a solvent in dry-cleaning and in fire extinguishers. It is listed as a cancer-causing chemical under Proposition 65.
A cancer-causing substance.
A hard, brittle, grayish heavy metal used in tanning, in paint formulation, and in plating metal for corrosion protection. It is toxic at certain levels and, in its hexavalent (versus trivalent) form, chromium is listed as a cancer-causing agent under Proposition 65.
A federal law passed in 1955 and extensively modified in 1970. It is enforced by the California Air Resources Board and the local air quality management or air pollution control districts, as well as by U.S. EPA nationally.
A federal law of 1977 enforced by U.S. EPA. A key provision is that "any person responsible for the discharge of a pollutant or pollutants into any waters of the United States from any point source must apply for and obtain a permit." This is reflected by the National Pollutant Discharge Elimination System (NPDES), through which the permits are issued by Regional Water Quality Control Boards. Permits are now being required for stormwater runoff from cities and other locations.
A comprehensive program for the clean-up (remediation) of a contaminated site. It involves investigation, analysis, development of a cleanup plan and implementation of that plan.
Combustible vapor mixture
The composition range over which air containing vapor of an organic compound will burn or even explode when set off by a flame or spark. Outside that range the reaction does not occur, but the mixture may nevertheless be hazardous because it does not contain enough oxygen to support life, or because the vapor is toxic.
Also known as Superfund, this Federal law authorizes U.S. EPA to respond directly to releases of hazardous substances that may endanger public health or the environment. The Superfund Amendments and Reauthorization Act of 1986 (SARA), amended and reauthorized CERCLA for five years at a total funding level of $8.5 billion. SARA also strengthened state involvement in the cleanup process, and encouraged the use of new treatment technologies and permanent solutions. CERCLA has since been extended by other laws. In particular, SARA Title III is known as the Emergency Planning and Community Right-to-Know Act of 1986. It requires each state to have an emergency response plan as described, and any company that produces, uses or stores more than certain amounts of listed chemicals must meet emergency planning requirements, including release reporting.
The amount of one substance in another substance. For example, a concentration of 10 milligrams per liter means there are 10 milligrams of a substance in 1 liter of another substance.
A legal document, approved and issued by a judge, formalizing an agreement between DTSC and the parties potentially responsible for site contamination. The decree describes cleanup and other actions that the potentially responsible parties are required to perform and the costs incurred by the government that they will reimburse, together with the roles, responsibilities and enforcement options that the government may exercise in the event of non-compliance. If a settlement between DTSC and a potentially responsible party includes cleanup actions, it must be in the form of a consent decree, which is subject to a public comment period.
Confining layer (confining bed)
A layer or bed of impermeable or distinctly less permeable material lying below or above one or more aquifers. When the confining layer lies between two aquifers, it keeps water from the upper aquifer separated, or confined, from water in the lower aquifer.
Enclosing or containing hazardous substances in a structure to prevent the migration of contaminants into the environment.
Any physical, chemical, biological, or radiological substance or matter that has an adverse effect on air, water, or soil.
A characteristic of acidic and basic hazardous wastes. The characteristic is defined by a waste's pH and its ability to corrode steel. A waste is corrosive if it has a pH less than or equal to 2.0 or greater than or equal to 12.5.
Air pollutants for which standards for safe levels of exposure have been set under the Clean Air Act. Current criteria pollutants are sulfur dioxide, particulate matter, carbon monoxide, nitrogen oxides, ozone and lead.
The term cumulative impact is used in several ways: as the effect of exposure to more than one compound; as the effect of exposure to emissions from more than one facility; the combined effects of a facility and surrounding facilities or projects on the environment; or some combination of these.
A notice placed on a property deed to alert future buyers about contamination on a property.
A legal restriction placed on a property deed to restrict future uses of a contaminated property. For example, a deed restriction may prohibit future housing development on a contaminated industrial site, or prohibit use of contaminated groundwater on a piece of property.
To remove grease from machinery, tools, etc., usually using solvents. Aqueous (water-based) cleaners are becoming popular and are required in some parts of the state.
Dense non-aqueous phase liquid
A liquid that is denser than water and does not dissolve or mix easily in water (is immiscible). Many chlorinated solvents such as trichloroethylene are DNAPLs.
Water which has been specifically treated to remove minerals.
A department within the California Environmental Protection Agency charged with the regulation of hazardous waste from generation to final disposal, and for overseeing the investigation and clean-up of hazardous waste sites.
The opposite of adsorption or absorption; molecules detach from a surface (such as soil particles).
Destruction and removal efficiency (DRE)
A percentage that represents the number of molecules of compound removed or destroyed in an incinerator relative to the number of molecules that entered the incinerator system. A DRE of 99.99 percent means that 9,999 molecules of a compound are destroyed for every 10,000 molecules that enter the system. For some compounds a DRE of 99.9999 is required.
The lowest concentration of a chemical that can be reliably measured by a given laboratory testing method.
To remove water from wastes, soils or chemicals.
A group of generally toxic organic compounds that may be formed as a result of incomplete combustion (as may occur in incineration of compounds containing chlorine). RCRA regulations require a higher destruction and removal efficiency (DRE) for dioxins and related furans (99.9999 percent) burned in incinerators than the DRE required for most other organic compounds (99.99 percent). They are rapidly absorbed through the skin and gastrointestinal tract and are listed as cancer-causing chemicals under Proposition 65.
The direction in which groundwater flows.
The vertical drop in the height between the water level in a well prior to pumping, and the water level in the well during pumping.
Dual-Phase Vacuum Extraction System
A treatment system designed to remove both contaminated groundwater and soil gas from a common groundwater well or wells. By removing ground-water, the system lowers the groundwater level around the well, allowing a strong vacuum to be applied to remove contaminated soil gas. The contami-nated water and air can then be removed or treated and released.
Duplicate Sample (Dupe)
A sample taken at the same location as another sample. Both samples are tested for chemicals. Taking a duplicate sample helps to ensure that testing procedures are precise: because the samples were taken in the same location, the samples should contain similar levels of chemicals.
Wastewater, treated or untreated, that flows out of a treatment plant, sewer or industrial outfall. Generally refers to wastes discharged into surface waters.
EPCRA (Emergency Planning and Community Right-to-Know Act)(SARA Title III)
See Comprehensive Environmental Response, Compensation, and Liability Act of 1980.
Estuary (adj.: estuarine)
Areas where fresh water from rivers mixes with salt water from nearshore ocean. They include bays, mouths of rivers, salt marshes and lagoons. These brackish water ecosystems shelter and feed marine life, birds and wildlife.
Used in the manufacture of a wide variety of industrial compounds and in certain cosmetics. It is used most commonly as an automobile antifreeze. It is toxic.
Existing or hypothetical routes by which chemicals in soil, water or other media can come in contact with humans, animals or plants.
Wells that are used primarily to remove contaminated groundwater from the ground. Water level measurements and water samples can also be collected from extraction wells.
Outside the original location. For example, contaminated that soil is dug up and removed before it is treated is being treated ex-situ. This is the opposite of in-situ.
A discharge well used to remove contaminated groundwater or air.
An evaluation of the alternatives for remediating any identified soil or groundwater contamination.
A class of compounds that ignite easily and burn rapidly. The Department of Transportation requires that Vehicles transporting flammables must have special markings (placards).
The outline of an area within which hazardous substances are suspected or known to exist.
Gas venting system
A system of pipes and vents installed in a landfill to prevent the build up of landfill gases, such as methane, that could potentially explode. Sometimes the gas vents have flares on them to burn the gas as it is released into the atmosphere. At some very large landfills, the gas is collected and used to generate electricity.
A low permeability plastic sheet that is placed over a landfill to deter rain and snow from entering a landfill's waste. Geomembranes are often made from a plastic called HDPE (high density polyurethane). The geomembrane is covered with soil (barrier protection layer) and top soil to protect it.
A general term that encompasses all techniques for determining whether a subsurface geological formation may be sufficiently porous or permeable to serve as an aquifer. These techniques typically involve lowering a sensing device into a borehole to measure properties of the subsurface formation.
A special machine used to make soil borings and to create temporary groundwater monitoring wells.
The unit of mass in the metric system. An ounce is about 28 grams, and a pound is approximately 450 grams.
Granular activated carbon (GAC)
A form of crushed and hardened charcoal. GAC has a strong potential to attract and absorb volatile organic compounds from extracted groundwater and gases.
Water found beneath the earth's surface that fills pores between soil particles such as sand, clay, and gravel or that fills cracks in bedrock. Precipitation that does not evaporate or runoff to surface waters percolates downward through soil and becomes groundwater. Groundwater flows from areas of high elevation to low elevation at generally low velocities (usually ranging from 10-1000 feet/year) and eventually discharges into surface waters such as rivers, lakes, and wetlands. Groundwater often provides a source of drinking water via wells. The chemical composition of the groundwater reflects the soil or bedrock through which it passes; groundwater dissolves minerals in the soil and bedrock. If a source of contamination exists at or below the earth's surface, percolating rainfall or snowmelt can transport contaminants downward where they can migrate with the groundwater.
Groundwater collection/extraction and treatment system (GWETS)
A system of wells fitted with pumps and piping used to pump out or extract contaminated groundwater from the subsurface. Properly designed and operated systems can effectively contain a groundwater contaminant plume and prevent further contaminant migration.
The family of elements that includes fluorine, chlorine, bromine and iodine. Halogens are very reactive and have man industrial uses. They are also commonly used in disinfectants and insecticides. Many hazardous organic chemicals -- such as polychlorinated biphenyls (PCBs), some volatile compounds (VOCs) and dioxins contain halogens, especially chlorine.
(1) Under the Comprehensive Environmental Response, Compensation, and Liability Act, a hazardous substance is any element, compound, mixture, solution, or substance that, when released to the environment, may present a substantial danger to the public health or welfare or to the environment, including, but not limited to, toxic and certain other pollutants under the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, hazardous air pollutants regulated by parts of the Clean Air Act, and Toxic Substance Control Act. The term is much broader than the term hazardous waste. Sites that contain only hazardous substances are excluded from New York's Superfund program. (2) Any substance designated reportable by the EPA if a designated quantity of the substance is spilled in the waters of the United States or if it is otherwise emitted to the environment.
Waste substances which can pose a substantial or potential hazard to human health or the environment when improperly managed. Hazardous waste possesses at least one of these four characteristics: ignitability, corrosivity, reactivity or toxicity; or appears on special U.S. EPA lists.
Health risk/endangerment assessment
A study prepared to assess health and environmental risks due to potential exposure to hazardous substances.
Health-based remediation targets
Levels to which hazardous substances on the site will be cleaned up. These target levels are health-based, meaning that exposure to the hazardous substances at or below the target is not expected to present a significant health risk.
Health and safety plan
A plan included in investigation or cleanup work plans which outlines protective measures for site workers and the community during investigation or cleanup activities.
A group of elements (such as chromium, lead, copper and zinc) that can be toxic at relatively low concentrations and tend to accumulate in the food chain.
Extraction and monitoring wells are typically drilled vertically. A horizontal well has the advantage of providing a large area of groundwater capture for a lower overall cost.
In general, the direction of groundwater flow due to changes in the depth of the water table. Just as water flows downhill, water in the ground moves from areas of high elevation to areas of low elevation. The slope of the water table is the hydraulic gradient. The hydraulic gradient determines the speed of groundwater flow. A steep gradient causes groundwater to mover faster than a nearly horizontal gradient.
An organic chemical compound of hydrogen and carbon in either gaseous, liquid, or solid phase. The molecular structure of hydrocarbon compounds varies from the simple (eg, methane, a constituent of natural gas) to the very heavy and very complex.
Clear, colorless and acidic solution of hydrogen chloride in water often used in metal cleaning and electroplating. Many hazardous wastes contain chlorine compounds which create small amounts of hydrogen chloride when they are burned. This can contribute to the formation of acid rain. Regulations require that air pollution control equipment remove either 99% of the hydrochloric acid, or that the emissions contain less than four pounds per hour.
Hydrogen Release Compound (HRC™)
Hydrogen Release Compound (HRC™) is a passive treatment option for bioremediation of chlorinated solvents. HRC™ is injected into contaminated soils. Naturally occurring microbes metabolize lactic acid released by HRC™, and produce hydrogen. The resulting hydrogen can be used to break down the chlorinated solvents. The process requires anaerobic conditions. Major target compounds include perchloroethene, trichloroethene, and trichloroethane as well as their breakdown products.
The geology of groundwater, with particular emphasis on the chemistry and movement of water.
The study of the movement and properties of water on the earth's surface, underground and in the atmosphere.
Unable to be penetrated, as by liquids. For example, an "impermeable membrane" can be a thin plastic sheet through which rainwater cannot move.
Refers to remediation work carried out without moving soil or displacing existing structures or buildings. An example of an in-situ remediation process is soil vapour extraction.
In-situ soil aeration
Applying a vacuum to vapor extraction wells to draw air through the soil so that chemicals in the soil are brought to the surface where they can be treated.
Chemicals selected from the group of chemicals found at the site and used for a public health evaluation. They are selected on the basis of toxicity, mobility and persistence, and are thought to be the chemicals of the greatest potential risk.
Interim Remedial Action Plan (IRAP)
A plan outlining cleanup actions taken to protect public health and the environment while long-term solutions are being developed.
A chemical that can cause temporary irritation at the site of contact.
Typically, water that has come in contact with hazardous wastes. For example: Water from rain or other sources that has percolated through a landfill and dissolved or carries various chemicals, and thus could spread contamination. Current landfills have systems to collect leachate before that can happen.
A heavy metal present in small amounts everywhere in the human environment. Lead can get into the body from drinking contaminated water, eating vegetables grown in contaminated soil, or breathing dust when children play or adults work in lead-contaminated areas or eating lead-based paint. It can cause damage to the nervous system or blood cells. Children are at highest risk because their bodies are still developing. Lead and its compounds are listed as a reproductive toxic substance for women and men, and a cancer-causing substance under Proposition 65.
Light non-aqueous phase liquid
(LNAPL) Liquids lighter than water that represent a special class of soil and groundwater contaminants with unique behavior and problems.
A magnetometer is an instrument that can detect metal objects buried underground. When this instrument is used to look for buried drums or other metal objects at a hazardous waste site, this is called a magnetometer survey.
Maximum contaminant level (MCL)
A contaminant level for drinking water, established by the California Department of Health Services, Division of Drinking Water and Environmental Management, or by the U.S.Environmental Protection Agency. These levels are legally-enforceable standards based on health risk (primary standards) or non-health concerns such as odor or taste (secondary standards).
Also known as "quicksilver," this metal is used in the paper pulp and chemical industries, in the manufacture of thermometers, and thermostats, and in fungicides. Mercury exists in three biologically important forms, elemental, inorganic and organic. It is highly toxic and affects the nervous system, kidneys and other organs. It also accumulates in animals that are high in the food chain (predators). Organic mercury compounds are the most toxic, and transformations between the three forms of mercury do occur in nature.
An odorless, colorless, flammable gas that is the major constituent of natural gas. It can be formed from rotting organic matter (i.e., trash in a landfill), and seep up through soils or migrate through underground piping to the surface. It also seeps up through the ground in areas that have shallow petroleum deposits or improperly abandoned oil wells, such as certain areas of the Los Angeles Basin. If it collects in a closed space and reaches certain concentrations, a spark can cause an explosion. It can also displace air and cause a suffocation hazard in low, enclosed spaces. This is one of the reasons landfill gas is collected and burned, sometimes for generation of electricity.
Microgram per gram (µg/g)
A measurable unit of concentration for a solid. A mercury level of 1.0 µg/g means that one microgram (one millionth of a gram) of mercury was detected in one gram of sample. It is equivalent to one part per million.
Milligram per cubic meter (mg/m^3 )
A unit of concentration for air contaminants. A mercury vapor level of 1.0 mg/m 3 means that one milligram (one thousandth of a gram) of mercury vapor was detected in each cubic meter of sampled air.
Milligram per kilogram (mg/kg)
A unit of concentration for a solid. A mercury level of 1.0 mg/kg in fish means that one milligram (one thousandth of a gram) of mercury was found in each kilogram of sampled fish. (A kilogram is 1,000 grams or approximately 2.2 pounds). Also equals one part per million.
The movement of chemical contaminants through soils or groundwater.
Actions taken to improve site conditions by limiting, reducing or controlling hazards and contamination sources.
Specially-constructed wells used exclusively for testing water quality.
A system under the federal Clean Water Act that requires a permit for the discharge of pollutants to surface waters of the United States. In California, NPDES permits are obtained from the Regional Water Quality Control Board.
The U.S. Environmental Protection Agency's list of the most serious uncontrolled or abandoned hazardous waste sites identified for possible long-term remedial response using money from a special trust fund (Superfund).
Relying on natural (physical, chemical, or biological) processes to reduce mass, toxicity, mobility, volume or concentration of compounds in earth or groundwater. Under proper conditions, can be used for perchloroethylene (PCE), trichloroethylene (TCE), and trichloroethane (TCA) at a lower cost than conventional remediation technologies.
A California Environmental Quality Act document issued by the lead regulatory agency when the initial environmental study reveals no substantial evidence that the proposed project will have a significant adverse effect on the environment, or when any significant effects would be avoided or mitigated by revisions agreed to by the applicant.
A metal used in alloys to provide corrosion and heat resistance for products in the iron, steel and aerospace industries. Nickel is used as a catalyst in the chemical industry. It is toxic and, in some forms, is listed as a cancer-causing agent under Proposition 65.
Formed when ammonia is degraded by microorganisms in soil or groundwater. This compound is usually associated with fertilizers.
Non-aqueous phase liquids (NAPL)
Liquids, commonly a mixture of several different chemicals, that are either denser or less dense than water. Dense NAPL (DNAPL), such as chlorinated solvents, will sink if it enters groundwater; less dense, or light NAPL (LNAPL), such as gasoline, will float on the water table. NAPL in the subsurface can be a persistent source of groundwater contamination due to its low solubility and viscosity.
The rock and soil in the ground above bedrock.
A group of chemicals that are very reactive, often but not always supplying oxygen to a reaction. Some oxidation reactions can release large amounts of heat and gases, and, under the right conditions, cause an explosion. Others can cause rapid corrosion of metal, damage to tissue, burns and other serious effects. Examples of oxidizers include chlorine gas, nitric acid, sodium perchlorate, and ammonium nitrate.
Ozone and ozonation
Ozone is a reactive form of oxygen (O3) that reacts with volatile organic compounds (VOCs) to change them into chemicals which pose no potential threat to human health, by breaking them down to form carbon dioxide and water. This is done with an ozonation unit.
Fine liquid or solid particles such as dust, smoke, mist, fumes, or smog, found in air or emissions.
Parts per million (ppm)
A measuring unit for the concentration of one material in another. When looking at contamination of water and soil, the toxins are often measured in parts per million. One part per million is equal to one thousandth of a gram of substance in one thousand grams of material. One part per million would be equivalent to one drop of water in twenty gallons. See milligrams per kilogram.
Parts per billion (ppb)
A unit of measure used to describe levels or concentrations of contamination. A measure of concentration, equaling 0.0000001 percent. For example, One part per billion is the equivalent of one drop of impurity in 500 barrels of water. Most drinking water standards are ppb concentrations.
Water that accumulates beneath the earth's surface but above the main water bearing zone (aquifer). Typically, perched groundwater occurs when a limited zone (or lens) of harder, less permeable soil is "perched" in otherwise porous soils. Rainwater moving downward through the soil stops at the lens, flows along it, then seeps downward toward the aquifer.
A volatile organic compound used primarily as a dry-cleaning agent. It is often referred to as "perc." It is toxic and listed as a cancer-causing chemical under Proposition 65.
The downward flow or filtering of water or other liquids through subsurface rock or soil layers, usually continuing to groundwater.
Chemical substances produced from petroleum in refinery operations. Many are hazardous.
A convenient way of describing the strength of an acidic or basic aqueous solution. The values range from 0 to 14, with a pH of 7 corresponding to neutral. As the pH number becomes smaller by one unit, the acidity increases by a factor of 10 (for 2 units, it changes by 100, and so on). Likewise, as the pH number increases by one unit, the alkalinity (basic property) increases by a factor of 10, etc.; tap water may lie in a region from above 6 to below 8. Strongly acidic waste solutions (pH less than 2) and strongly basic ones (pH greater than 12.5) are defined as hazardous wastes because of their corrosive effect on metals and on skin. See Acid, Alkaline, Base.
Organic compounds used in plastics manufacturing, tanning, and textile, dye and resin manufacturing. They are by-products of petroleum refining. In general, they are highly toxic.
An instrument used to measure the elevation of the water table, i.e. how far below the surface groundwater is located.
A study of a possible cleanup alternative during the Feasibility Study for a specific site. It is used to gather data necessary for the final selection of the cleanup method.
An area of chemicals moving away from its source in a feather-like (hence the name, plume) shape. Often a body of contaminated groundwater flowing from a specific source, the movement of which is influenced by such factors as local groundwater flow patterns, the character of the aquifer in which the groundwater is contained, and the density of contaminants. A plume may also be a cloud of smoke or vapor. It defines the area where exposure would be dangerous.
Polychlorinated biphenyls (PCBs)
A group of toxic chemicals used for a variety of purposes including electrical applications, carbonless copy paper, adhesives, hydraulic fluids, and caulking compounds. PCBs do not breakdown easily and are listed as cancer-causing agents under Proposition 65.
Polynuclear aromatic hydrocarbons (PAHs or PNAs)
PNAs or Polynuclear Aromatic Hydrocarbons, are natural constituents of crude oil, and also may be formed when organic materials such as coal, oil, fuel, wood or even foods are not completely burned. PNAs are also found in lampblack, a by-product of the historic gas manufacturing process. PNAs are found in a wide variety of other materials, including diesel exhaust, roofing tars, asphalt, fireplace smoke and soot, cigarettes, petroleum products, some foods, and even some shampoos. PNAs tend to stick to soil and do not easily dissolve in water, and generally do not move in the environment. The test method used to analyze for PNAs detects seventeen different compounds. Of the seventeen, seven are suspected of causing cancer in humans.
Polyvinyl chloride (PVC)
A plastic made from the gaseous chemical vinyl chloride. PVC is used to make pipes, records, raincoats and floor titles. It produces hydrochloric acid when burned. Health risks from high concentrations of vinyl chloride (not the polymer) include liver cancer and lung cancer, as well as cancer of the lymphatic and nervous systems. Vinyl chloride (not the polymer) is listed as a cancer-causing chemical under Proposition 65.
Potentially Responsible Party (PRP)
An individual, company or government body identified as potentially liable for a release of hazardous substances to the environment. By federal law, such parties may include generators, transporters, storers and disposers of hazardous waste, as well as present and past site owners and operators.
A wastewater treatment unit that is designed to treat wastewater that does not meet the sewage discharge standards so that it meets or exceeds those standards. Pretreatment units usually require a permit from a local agency.
Principal organic hazardous constituents (POHCs)
Specific hazardous compounds monitored during an incinerator, boiler or industrial furnace trial burn. They are selected on the basis of their high concentration in the waste feed and the difficulty of burning them.
A field test by which a well is pumped for a period of time and data are collected for use in assessing characteristics of subsurface water-bearing zones, or aquifers.
Quality assurance quality control (QA)/(QC)
A system of procedures, checks, audits, and corrective actions to ensure that environmental sampling and testing are of the highest achievable quality.
A gaseous, radioactive alpha particle-emitting element with a half-life of about four days. Radon exists naturally in many locations, and may present a serious health risk when it accumulates in basements or crawl spaces beneath homes.
A class of compounds which are normally unstable and readily undergo violent change, react violently with water, can produce toxic gases with water, or possess other similar properties. Reactivity is one characteristic that can make a waste hazardous.
Regional Water Quality Control Board (RWQCB)
Agencies that maintain water quality standards for areas within their jurisdictions and enforce state water quality laws.
Remedial Action Plan (RAP)
A plan that outlines a specific program leading to the remediation of a contaminated site. Once the Draft Remedial Action Plan is prepared, and approved by DTSC a public meeting is held and comments from the public are solicited for a period of not less then 30 days. After the public comment period has ended and the comments have been responded to in writing, DTSC may modify the Draft Plan on the basis of those comments before it approves the final remedy for the site (the Final RAP).
Remedial Investigation/Feasibility Study (RI/FS)
A series of investigations and studies to identify the types and extent of chemicals of concern at the site and to determine cleanup criteria (Remedial Investigation), and to provide an evaluation of the alternatives for remediating any identified soil or groundwater problems (Feasibility Study).
Cleanup of a site to levels determined to be health-protective for its intended use.
A 1976 amendment to the first federal solid waste legislation, the Solid Waste Disposal Act of 1965. In RCRA, Congress established initial directives and guidelines for U.S. EPA to regulate and managesolid waste, including hazardous waste. RCRA established a regulatory system to track hazardous substances from the time of generation to final disposal. The law requires safe and secure procedures to be used in treating, transporting, storing and disposing of hazardous wastes. RCRA was designed to prevent new, uncontrolled hazardous waste sites.
An individual or corporate entity considered legally liable for contamination found at a property and, therefore, responsible for cleanup of the site.
A risk assessment looks at the chemicals detected at a site, the frequency and concentration of detected chemicals, the toxicity of the chemicals and how people can be exposed, and for how long. Routes of exposure to people are generally through ingestion, such as eating, contact with the skin, or inhalation. The most significant potential routes of exposure are trough ingestion and contact with the skin. Based on the standard risk assessment guidelines established for use nationwide by U.S. EPA, exposures for an on-site resident are generally assumed to e daily contact over a 30-year period starting with children ages 0-6, and continuing from 6-30 years. The health risk assessment cannot predict health effects; it only describes the increased possibility of adverse health effects, based on the best scientific information available.
Small amounts of air, water, or soil are obtained and tested to determine the levels of different hazardous chemicals contained in them.
A landfill which does not take hazardous waste, often called a "garbage dump." It must be covered with dirt each day to maintain sanitary conditions. The Integrated Waste Management Board regulates these facilities.
See Superfund Amendments and Reauthorization Act of 1986.
See Comprehensive Environmental Response, Compensation and Liability Act of 1980.
A subsurface area in which all pores and cracks in rock and/or soil are filled with water.
A device for removing unwanted gases or particles from an air stream by spraying the air with liquid (usually water) or forcing air through a series of baths. Scrubbers are often put on smoke stacks.
A structure designed to capture spills or leaks, as from a container or tank. For containers and aboveground tanks, it is usually a bermed area of coated concrete. For underground tanks, it may be a second, outer, wall or a vault. Construction of such containment must meet certain requirements, and periodic inspections are required.
The soil, sand and minerals at the bottom of surface waters, such as streams, lakes and rivers. Sediments capture or adsorb contaminants. The term may also refer to solids that settle out of any liquid.
Semivolatile organic compounds (SVOCs)
Compounds that evaporate slowly at normal temperatures.
A depression formed when the surface collapses into a cavern.
Site mitigation process
The regulatory and technical process by which hazardous waste sites are identified and investigated, and cleanup alternatives are developed, analyzed, decided upon and applied.
A watery mixture that does not contain a significant amount of dissolved materials.
Barriers used to contain the flow of contaminated groundwater or subsurface liquids. Slurry walls are constructed by digging a trench around a contaminated area and filling the trench with a material that tends not to allow water to pass through it. The groundwater or contaminated liquids trapped within the area surrounded by the slurry wall can be extracted and treated.
Soil samples taken by drilling a hole in the ground.
Soil gas survey
Soil gas or (soil vapor) is air existing in void spaces in the soil between the groundwater and the ground surface. These gases may include vapor of hazardous chemicals as well as air and water vapor. A soil-gas survey involves collecting and analyzing soil-gas samples to determine the presence of chemicals and to help map the spread of contaminants within soil.
Soil vapor extraction (SVE)
A process in which chemical vapors are extracted from the soil by applying a vacuum to wells. An in-situ remediation technique that applies a vacuum to a series of wells ("vapor extraction wells") and induces air flow through contaminated soil. As the air migrates through the soil, volatile organic compounds (VOCs) volatilize (evaporate) and move with the air to the extraction wells where they are removed from the subsurface. If the concentration of VOCs in the extracted air is high, the air maybe treated by a carbon adsorption system before being released to the atmosphere. In some cases, dual phase vacuum extraction is used to treat both groundwater and the overlying soil.
Mixing additives, such as fly ash or cement, with soil containing hazardous chemicals, especially metals, to make it more stable. This process lessens the risk of exposure to the hazardous chemicals by making it less likely that those chemicals will move into and through surface or groundwater.
Soluble Threshold Limit Concentration (STLC)
The limit concentration for toxic materials in a sample that has been subjected to the California Waste Extraction Test (WET), a state test for the toxicity characteristic that is designed to subject a waste sample to simulated conditions of a municipal waste landfill. If the concentration of a toxic substance in the special extract of the waste exceeds this value, the waste is classified as hazardous in California. This is distinct from the Total Threshold Limit Concentration (TTLC).The California Waste Extraction Test procedure is more stringent than the federal Toxicity CharacteristicLeaching Procedure (TCLP).
A liquid capable of dissolving another substance to form a solution. Water is sometimes called "the universal solvent" because it dissolves so many things, although often to only a very small extent. Organic solvents are used in paints, varnishes, lacquers, industrial cleaners and printing inks, for example. The use of such solvents in coatings and cleaners has declined over the last several years, because the most common ones are toxic, contribute to air pollution and may be fire hazards.
Changing active organic matter in sludge into inert, harmless material. The term also refers to physical activities such as compacting and capping at sites that limits the further spread of contamination without actual reduction of toxicity.
Suggested No Adverse Response Level (SNARL)
Drinking water standards established by the U.S. EPA, but not enforceable by law. SNARLs suggest the level of a containment in drinking water at which adverse health effects would not be anticipated (with a margin of safety).
A pit or tank that catches liquid runoff for drainage or disposal.
Federal and state programs to investigate and clean up inactive hazardous waste disposal sites. The federal program gives the U.S. Environmental Protection Agency the funding and authority to investigate, rank and con-duct or supervise cleanup of sites on the National Priority List. New York State's program gives DEC the same authority to deal with sites that do not qualify for the federal superfund list, but meet certain other qualifications.
Modifications to CERCLA enacted in 1986. Sometimes referred to as the "Right to Know Law," it requires, among other things, that industry provide the government with information on the use and release of certain chemicals into the environment. This information is then made available to the public.
A tank used to absorb irregularities in flow of liquids, including liquid waste materials, so that the flow out of the tank is constant.
Volatile organic compound that is commonly used as an industrial degreasing solvent. TCE affects the central nervous system and is listed as a cancer-causing chemical under Proposition 65.
Tetrachlorophenol is a toxic fungicide.
A toxic volatile organic compound often used as an industrial solvent.
A federal law of 1976 to regulate chemical substances or mixtures that may present an unreasonable risk of injury to health or the environment.
Ability to harm human health or environment, such as injury, death or cancer. One of the criteria that is used to determine whether a waste is a hazardous waste (the "Toxicity Characteristic").
An aquifer in which water is not contained by an impermeable layer of rock or soil. The water level in the aquifer may rise or fall according to the volume of water stored, which varies according to seasonal cycles of natural recharge.
Underground Storage Tank (UST)
Underground tank made of steel or fiberglass commonly used to store gasoline and diesel products.
Underground soil and gravel that could contain groundwater, but lies above the aquifier. This is in contrast to a saturated zone, where the space between soil particles is filled with water.
The direction from which water flows in an aquifer. In particular, areas that are higher than contaminated areas and, therefore, are not prone to contamination by the movement of polluted groundwater.
The unsaturated zone which occurs above the water table where the soil pores are only partially filled with water (the moisture content is less than the porosity). This zone is limited above by the land surface and below by the surface of the saturated zone, that is, the water table.
A method for close-up inspection of the interior of a well or pipe by means of a color camera that can view the well casing and screen at 90 degrees to the well's axis.
Vinyl chloride is widely used in the plastics industry in creating polyvinyl chloride (PVC). It is listed as a cancer-causing agent under Proposition 65.
A measure of the ease with which a liquid can be poured or stirred. The higher the viscosity, the less easily a liquid pours.
The space in a tank between the top of a tank and the liquid level. If the tank is used to store combustible liquids that easily evaporate, this space can fill with vapors which may reach explosive levels.
Describes substances that readily evaporate at normal temperatures and pressures.
Volatile organic compounds (VOCs)
Organic liquids, including many common solvents, that readily evaporate at temperatures normally found at ground surface and at shallow depths. They take part in atmospheric photochemical (lights-driven) reactions to produce smog.
In a shallow aquifer, a water table is the depth at which free water is first encountered in a monitoring well. The boundary between the unsaturated zone and the saturated zone.The water table generally reflects surface topography and varies with changes in land surface elevations.
Surface drainage area that contributes water to a lake, river, or other body of water.
The site work plan describes the technical activities to be conducted during the various phases of a remediation project.
An aromatic hydrocarbon used in gasoline, paints, lacquers, pesticides, gums, resins and adhesives. It is toxic and flammable.
A metal used for auto parts, for galvanizing, and in production of brasses and dry cell batteries. It is nutritionally essential but toxic at higher levels.